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    Radius Ratio Calculator

    For NaCl the radius ratio is 0.563536, between 0.414 and 0.732, so each ion has six neighbours in the rock-salt structure.

    Na⁺ 1.02 Å, Mg²⁺ 0.72 Å, Ca²⁺ 1.00 Å, Zn²⁺ 0.74 Å (six-fold).

    Cl⁻ 1.81 Å, O²⁻ 1.40 Å, F⁻ 1.33 Å, S²⁻ 1.84 Å.

    Radius ratio r_c/r_a =

    0.56353591160221

    Full answer, then cut to fewer decimals (not rounded):

    • 0.56353591160221
    • 0.5635359116022
    • 0.563535911602
    • 0.56353591160
    • 0.5635359116
    • 0.563535911
    • 0.56353591
    • 0.5635359
    • 0.563535
    • 0.56353
    • 0.5635
    • 0.563
    • 0.56
    • 0.5
    Predicted coordination number
    6
    Coordination polyhedron
    octahedral
    Typical structure
    NaCl (rock salt)
    Step-by-step solution
    1. r_c/r_a = 1.02 ÷ 1.81 = 0.5635359116
    2. Limits: 0.155 (CN 3), 0.225 (CN 4), 0.414 (CN 6), 0.732 (CN 8), 1 (CN 12)

    Radius Ratio Formula

    r_c / r_a → coordination number

    limits 0.155 (3), 0.225 (4), 0.414 (6), 0.732 (8), 1.0 (12)

    Worked Example

    Sodium chloride: Na⁺ 1.02 Å and Cl⁻ 1.81 Å:

    1. r_c/r_a = 1.02 ÷ 1.81 = 0.5635359116
    2. Limits: 0.155 (CN 3), 0.225 (CN 4), 0.414 (CN 6), 0.732 (CN 8), 1 (CN 12)

    Coordination polyhedron: octahedral · Typical structure: NaCl (rock salt)

    GATE tip

    Electroneutrality fixes the formula: in CaF₂, Ca²⁺ has 8 F⁻ neighbours and each F⁻ has 4 Ca²⁺, the ratio of their coordination numbers matching 1 : 2.

    More Processing and Materials Calculators

    Frequently asked questions

    Where do the limits come from?

    Each limit is the ratio at which the cation just touches all its anion neighbours in that polyhedron; for octahedral coordination it is √2 − 1 = 0.414.

    Is the rule always right?

    It is a guide: covalent bonding and polarisation can change the structure, as in ZnS, which is tetrahedral despite a ratio near 0.4.

    Sources

    Last reviewed: . Factors are stored exactly and computed with 50-digit decimal arithmetic. See how we verify conversion factors.

    Cite this page

    APA

    Scientific Converters. (2026, October 15). Radius Ratio Calculator. Retrieved October 25, 2026, from https://scientificconverters.com/calculators/radius-ratio-calculator/

    IEEE

    Scientific Converters, "Radius Ratio Calculator," scientificconverters.com. Accessed: Oct. 25, 2026. [Online]. Available: https://scientificconverters.com/calculators/radius-ratio-calculator/

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